Blair and Chuck are listed at Starpulse’s Best TV Couples That Aren’t Together – But Should Be.

They’re Chuck (Ed Westwick) and Blair (Leighton Meester). Blair and Chuck. The most devious, screwed up pair of romantics on the Upper East Side. She is the Queen B, a masterful manipulator with the heart of a lonely insecure little girl. He is a decadent womanizer endlessly searching for his cold daddy’s approval and never getting it. It was pretty shocking when this pair hooked up for the first time, especially considering she broke up with his best friend Nate only a few hours earlier, but they took over “Gossip Girl” ever since. No one can stop watching this not-really-a-couple try to one up each other as proof of their twisted love, and it sadly has come to an end…for now. Chuck promised that they were inevitable, and that someday in the future maybe they could be the real thing. Can that future be now, please?